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Holmes
& Associates, Inc.
Ken Holmes, E.E., President
19916 Old Owen Road, Suite 177
Monroe, Washington 98272
Innovative
Electronic Design & Product Development
Phone:
(360) 793-9723 Email: kholmes@premier1.net Fax: (360) 793-0364
Medallion
Healthy Homes Ozone Study
There are two primary
methods used to produce ozone.
The first method uses
ultraviolet light. Each individual photon in a beam of ultraviolet
light contains only a certain amount of energy, due to its
spectral frequency and wavelength. This energy is just enough
to break apart the bonds between the two oxygen atoms in
an oxygen molecule. These atoms combine with two other oxygen
molecules to create two ozone molecules. The chemical reaction
is: 3 O2 + Energy = 2 O3. The energy of an ultraviolet light
photon is not sufficient to break apart the bond between
the two nitrogen atoms in a nitrogen molecule, or to create
the undesirable nitrous oxides or nitric acid. This is why
the ozone produced by the ultraviolet light method has a
"sweet, fresh, and clean" smell. Generating ozone
by the ultraviolet light method is a "controlled process",
since variations in the AC line voltage only affects the
quantity of photons produced, and not the spectral frequency,
wavelength, or energy per photon. As a result, the ultraviolet
light method produces only clean, beneficial ozone.
The second method uses
high-voltage to create ozone. The high-voltage energy is
more intense than the ultraviolet light energy, and breaks
apart the nitrogen gas and water vapor molecules in the
air. This creates nitrous oxides, and nitric acid molecules,
which are harmful to human beings and to the environment.
"Smog" contains these molecules. These hazardous
side effects are always present to some extent, and are
inherent in the high-voltage method of ozone production.
As a result, the combination of gases produced by the high-voltage
method has an "acrid, pungent, or sharp" smell.
High-voltage is applied between two metal electrodes, plates,
foils, or screens, often separated by an insulator (which
needs occasional replacement, due to self-contamination
and degradation). This is actually an "uncontrolled
process", because the high-voltage varies with AC line
voltage spikes, transients, surges, regulation, load shedding,
and other factors. This is why professional, industrial
equipment manufacturers, which use the high-voltage method,
nearly always use pure, industrial or hospital-grade, oxygen
(not just air) flowing over the electrodes (in a special
reaction chamber) to help create a more or less nitrous-free
ozone. Using just air with the high-voltage method guarantees
the production of undesirable nitrous oxides, or nitric
acid molecules.
The high-voltage method has been described by various manufacturers'
advertising literature as "cold plasma", "corona
discharge", "arc discharge", "ionization",
"electric field", or other names. There are numerous
claims, counter-claims, and technical-sounding terms used
by these manufacturers. Many of these terms are confusing,
contradictory, or misleading. Understanding may seem like
an impossible task, requiring an advanced degree in chemistry
and physics.
Yet there is a way to
see through all these claims. Simply ask the manufacturer
to provide certified test data for the high-voltage ozone
generator, identifying the amount of every gas at the input,
and at the output. Any amount of nitrous oxides or nitric
acid output is undesirable. The percentage of trace gases
(argon, helium, etc.) at the input and the output should
be the same. If nitrogen and water vapor does not show up
in the test data, the data is questionable, since these
are both included in the air we breathe, and the ozone generator
does not eliminate them. Manufacturers of high-voltage ozone
generators (using just air) will not provide this data because
of the problems it would reveal.
It has been reported
that some high-voltage ozone generating equipment is being
used in just air, with a tube spraying raw oxygen from a
tank into the unit. This does not eliminate the nitrous
oxide problem, yet it does create a serious safety hazard.
There is an inherent potential problem in using raw oxygen
in and around high-voltage "sparking"/corona.
Even in the most controlled "safe" process, and
"explosion-proof" electrical applications, there
is still the danger of violent combustion and explosion.
That is why signs are posted near oxygen storage and use
areas: No Smoking; Danger, Oxygen Storage; Oxygen in Use;
or Danger, Oxygen. Spraying raw oxygen into a high-voltage
unit is neither controlled, safe, or explosion-proof. It
should be a prerequisite to post danger signs in several
languages, wherever such equipment is in use.
In summary, in an air
environment, the high-voltage method produces undesirable
and hazardous by-products. The high-voltage method with
an oxygen spray is dangerous. Ultraviolet light is the only
method of producing safe, clean, beneficial ozone.
Report dated April 24,
2003
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